The 2012 Johnnie Walker Championship at Gleneagles is the last European Tour event before the Ryder Cup team is named - and favourite Francesco Molinari starts his victory bid at 13:15 BST in the first round on Thursday.
The Italian will play in the same group as the only other man in the field who has secured his place in the European Ryder Cup team, Paul Lawrie, with Simon Dyson completing the three-ball.
Molinari is a best-priced 11/1 at
BetVictor to win the Johnnie Walker Championship, while Lawrie can be backed at 25/1 and Dyson 28/1 with the same bookmaker.
Nicolas Colsaerts can knock Martin Kaymer out of the top 10 in the Ryder Cup points table to qualify automatically for the team with a top-two finish at Gleneagles and the Belgian tees off at 08:15 BST with Thomas Bjorn and Stephen Gallacher.
Here is the full list of first-round tee times for the 2012 Johnnie Walker Championship (all times BST, players British or Irish unless stated):
07:25 (1st tee): James Byrne, Graham Fox, Roope Kakko (Fin)
07:35 (1st tee): Andrew Marshall, Rhys Davies, Warren Bennett
07:35 (10th tee): Gregory Bourdy (Fra), Lloyd Kennedy, Miles Tunnicliff
07:45 (1st tee): Phillip Price, Gareth Maybin, Jamie Moul
07:45 (10th tee): Chris Doak, Kenneth Ferrie, David Drysdale
07:55 (1st tee): George Murray, Gary Orr, Peter Hedblom (Swe)
07:55 (10th tee): Michael Hoey, Shaun Micheel (USA), Ross Fisher
08:05 (1st tee): Paul Waring, Estanislao Goya (Arg), Gary Boyd
08:05 (10th tee): Paul McGinley, David Lynn, Raphael Jacquelin (Fra)
08:15 (1st tee): Ricardo Gonzalez (Arg), Bradley Dredge, S S P Chowrasia (Ind)
08:15 (10th tee): Thomas Bjorn (Den), Stephen Gallacher, Nicolas Colsaerts (Bel)
08:25 (1st tee): David Dixon, Pablo Martin (Spa), Scott Henderson
08:25 (10th tee): Alexander Noren (Swe), Marcel Siem (Ger), Thorbjorn Olesen (Den)
08:35 (1st tee): Oliver Wilson, Tjaart van der Walt (Rsa), Marcus Both (Aus)
08:35 (10th tee): Rich Beem (USA), Marcus Fraser (Aus), Richie Ramsay
08:45 (1st tee): Alastair Forsyth, Tim Sluiter (Ned), Robert Coles
08:45 (10th tee): Jbe Kruger (Rsa), Simon Khan, Michael Campbell (Nzl)
08:55 (1st tee): Steven O'Hara, Sam Little, Jose Manuel Lara (Spa)
08:55 (10th tee): Andrew Johnston, Darren Fichardt (Rsa), Richard Finch
09:05 (1st tee): Keith Horne (Rsa), Andy Sullivan, Paul McKechnie
09:05 (10th tee): Matthew Zions (Aus), Carlos Del Moral (Spa), Thomas Norret (Den)
09:15 (1st tee): Romain Wattel (Fra), Ignacio Garrido (Spa), Peter Lawrie
09:15 (10th tee): Emanuele Canonica (Ita), Gareth Wright, Alex Haindl (Rsa)
09:25 (1st tee): Ricardo Santos (Por), Petr Gal (Cze), Reinier Saxton (Ned)
09:25 (10th tee): Oliver Fisher, Joel Sjoholm (Swe), Greig Hutcheon
09:35 (10th tee): Niclas Fasth (Swe), Steve Webster, Fabrizio Zanotti (Par)
12:25 (1st tee): Andrea Pavan (Ita), Markus Brier (Aut), Victor Riu (Fra)
12:35 (1st tee): Brett Rumford (Aus), Knut Borsheim (Nor), Federico Colombo (Ita)
12:35 (10th tee): Jack McDonald, Danny Denison, Craig Lee
12:45 (1st tee): Robert Rock, Mark Foster, Scott Jamieson
12:45 (10th tee): Bernd Ritthammer (Ger), Taco Remkes (Ned), Alejandro Canizares (Spa)
12:55 (1st tee): Darren Clarke, Jose Maria Olazabal (Spa), Johan Edfors (Swe)
12:55 (10th tee): Graeme Storm, Fredrik Andersson Hed (Swe), Damien McGrane
13:05 (1st tee): Rafa Cabrera Bello (Spa), Anders Hansen (Den), Miguel Angel Jimenez (Spa)
13:05 (10th tee): Richard McEvoy, Julien Quesne (Fra), Chris Wood
13:15 (1st tee): Paul Lawrie, Simon Dyson, Francesco Molinari (Ita)
13:15 (10th tee): Robert-Jan Derksen (Ned), Chris Gane, Alan Lockhart
13:25 (1st tee): Colin Montgomerie, Soren Kjeldsen (Den), Pablo Larrazabal (Spa)
13:25 (10th tee): Michael Jonzon (Swe), Peter Whiteford, Peter Gustafsson (Swe)
13:35 (1st tee): Tom Lewis, Marc Warren, Gregory Havret (Fra)
13:35 (10th tee): Scott Pinckney (USA), Edouard Dubois (Fra), Shiv Kapur (Ind)
13:45 (1st tee): Jamie Elson, Dylan Frittelli (Rsa), Lorenzo Gagli (Ita)
13:45 (10th tee): Tommy Fleetwood, Richard Bland, Grant Forrest
13:55 (1st tee): Oscar Floren (Swe), Matthew Baldwin, Felipe Aguilar (Chi)
13:55 (10th tee): Stephen Dodd, Mikko Ilonen (Fin), Mikael Lundberg (Swe)
14:05 (1st tee): Matthew Southgate, Lloyd Saltman, Joakim Lagergren (Swe)
14:05 (10th tee): David Howell, Richard Green (Aus), Scott Strange (Aus)
14:15 (1st tee): Jorge Campillo (Spa), Jean-Baptiste Gonnet (Fra), Victor Dubuisson (Fra)
14:15 (10th tee): Benjamin Hebert (Fra), Rikard Karlberg (Swe), Simon Thornton
14:25 (1st tee): Andrew Dodt (Aus), Adrian Otaegui (Spa), David Patrick
14:25 (10th tee): Sam Hutsby, Matthew Nixon, James Morrison
14:35 (10th tee): Emiliano Grillo (Arg), Maarten Lafeber (Ned), Stephen Gray
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